By Abhimanyu O. Patil, Donald N. Schulz, Bruce M. Novak
content material: useful polymers : an outline / D.N. Schulz and Abhimanyu O. Patil --
Synthesis of sensible polymers by means of atom move radical polymerization / Krzysztof Matyjaszewski, Veerle Coessens, Yoshiki Nakagawa, Jianhui Xia, Jian Qiu, Scott Gaynor, Simion Coca, and Christina Jasieczek --
useful polymers : random copolymers by means of good loose radical polymerization / Paula J. MacLeod, Gordon okay. Hamer, Pushpamma Lukose, and Michael okay. Georges --
Use of defending teams in polymerization / D.N. Schulz, S. Datta, and R.M. Waymouth --
Novel, secure functionalized initiators for anionic polymerizations / Douglas E. Sutton and James A. Schwindeman --
Anionic synthesis of hydroxyl-functionalized polymers utilizing safe, functionalized alkyllithium and isoprenyllithium initiators / Roderic P. Quirk, Sung H. Jang, Kwansoo Han, Huimin Yang, Brad Rix, and Youngjoon Lee --
Anionic synthesis of macromonomer sporting amino team utilizing diphenylethylene spinoff / Jungahn Kim, Jae Cheol Cho, Keon Hyeong Kim, Kwang Ung Kim, gained Ho Jo, and Roderic P. Quirk --
Functionalized polymers with dimethylamine and sulfozwitterionic end-group : synthesis, dilute resolution, and bulk homes / Nikos Hadjichristidis, Marinos Pitsikalis, and Stergios Pispas --
Novel useful copolymers via mixture of dwelling carbocationic and anionic polymerizations / Jesper Feldthusen, Bela Iván, and Axel H.E. Müller --
Synthesis and characterization of [alpha]-hydroxyl-[omega]-methoxycarbonyl and [alpha]-hydroxyl-[omega]-carboxyl uneven telechelic polyisobutylenes / Balint Koroskenyi and Rudolf Faust --
Organo infrequent earth steel initiated dwelling polymerizations of polar and nonpolar monomers / Hajime Yasuda, Eiji Ihara, Yuu Nitto, Takamaro Kakehi, Masakazu Morimoto, and Mitsufumi Nodono --
New reactive polyolefins containing p-methylstyrene starting from semicrystalline thermoplastics to amorphous elastomers / H.L. Lu and T.C. Chung --
a singular reactive functionalization of polyolefin elastomers : direct functionalization of poly(isobutylene-co-p-methylstyrene) by means of a Friedel-Crafts acylation response / Abhimanyu O. Patil --
New strategies through chemical alterations of polyolefins. half 1, Synthesis and houses of novel phosphonium ionomers from poly(isobutylene-co-4-bromomethylstyrene) / P. Arjunan, H-C. Wang, and J.A. Olkusz --
Multifunctional supramolecular fabrics / Gregory N. Tew and S.I. Stupp --
Weil-defined smectic C* part chain liquid crystalline polymers / Wen-Yue Zheng, Thomas Epps, David Wall, and Paula Hammond --
layout of assemblies of functionalized nanoscopic gridlike coordination arrays / Ulrich S. Schubert, Jean-Marie Lehn, Jörg Hassmann, Catherine Y. Hahn, Nikolaus Hallschmid, and Paul Müller --
practical polyphosphazenes / Harry R. Allcock --
Synthesis of biodegradable copolymers with pendant hydrophilic useful teams / S. Jin and K.E. Gonsalves --
Photoinitiated ring-opening polymerization of epoxidized polyisoprene / C. Decker and T. Hoang Ngoc --
Synthesis of cyclic carbonate useful polymers / Dean C. Webster and Allen L. Crain --
Functionalized polydiacetylenes with polar, hydrogen bonding and metal-containing teams / I.H. Jenkins, W.E. Lindsell, C. Murray, P.N. Preston, and T.A.J. Woodman.
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Additional info for Functional Polymers. Modern Synthetic Methods and Novel Structures
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77 CH2—Chfc>—(Chfc) n - O T M S Chfe—Chfe—(CH2) n—NRTMS (27) (28) Carboxyl monomers have been protected in several ways for Z - N polymerization. In one method, the carboxyl functionality is first converted to an ester group and subsequently precomplexed with an aluminum compound to further mute its reactivity with Z - N catalysts " . The precomplexed ester monomer (29) is stable to Z - N conditions and is removed during work-up. Of course, the ester groups can be further hydrolyzed to carboxylic acids or salts, which can associate via hydrogen bonding or ionic interactions.
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