By A.W. Parkins
This booklet provides an built-in view of the organometallic chemistry of transition and non-transition parts. Early chapters care for the fundamental ideas, guidance and constitution of organometallic compounds. next chapters speak about the reactivity of those compounds and the functions of organometallic compounds as stoichiometric reagents and catalysts. The textual content is comprehensively referenced all through and is usually a consultant to organometallic literature, expanding its usefulness to all these taken with the learn or educating of this more and more vital department of undergraduate chemistry.
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This ebook offers an built-in view of the organometallic chemistry of transition and non-transition parts. Early chapters take care of the fundamental rules, practise and constitution of organometallic compounds. next chapters speak about the reactivity of those compounds and the purposes of organometallic compounds as stoichiometric reagents and catalysts.
Extra resources for An Introduction to Organometallic Chemistry
Into Edn Engl. 16,870 40 AN INTRODUCTION TO ORGANOMETALLIC CHEMISTRY Fischer, Fischer, Fischer, Fischer, E. O. (1960). Inorg. Synth. 6, 132 E. O. (1976). Adv. organomet. Chem. 14,1 E. , and Milller, 1. (1962). Z. Naturforsch. B 17,776 E. , Kreissl, F. , and Kreiter, C. G. (1972). Chem. Ber. 105,588 Fischer, E. , Lindner, T. , Kreissl, F. , and Besenhard, 1. O. (1977). Chem. Ber. , and Tagliavini, G. 1. organomet. Chem. , and Crabtree, R. H. (1979). Inorg. Synth. 19,218 Halasa, A. , Schulz, D. , Tate, D.
Adv. organomet. Chem. -W. (1971). Z. Naturforsch. B 26, 66 Kramer, G. , and Brown, H. C. (1974). J. organomet. Chem. 73,1 Krief, A. (1980). Tetrahedron 36, 2596 Langer, A. W. ) (1974). Polyamine-chelated Alkali Metal Compounds, Advances in Chemistry Series, no. 130. C. Larock, R. C. (1976). J. organomet. Chem. Library 1,257 Lehmkuhl, H. (1973). Synthesis, 377 Lindley, P. , and Woodward, P. J. chem. Soc. (Aj 123 Luijten, J. G. , and van der Kerk, G. J. M. (1964). Rec. Trav. Chim. , and Shaw, B. L.
TThroughout this text bond distances have been given in imgstrom units, these being commonly accepted in structural chemistry although not SI units; 1 A = 10-10 m. , 1983). Gold alkyls adopt different geometries depending on the oxidation state. , 1971). However, Au(I1I) alkyls, which again require an additional ligand for stabilisation are square planar, as in IV (Baker and Pauling, 1969). There are /C 6 F S F S C6 , Cl/ Au '-PPh 3 IV III also many polynuclear compounds containing Au- C bonds, and some of these also contain direct Au-Au bonds.